2-methylheptane , octane and 2,2,4-trimethylpentane in order of increasing boiling point?

Good question. The boiling points of the alkanes should increase in the order, ##”2,2,4-trimethylheptane”##, ##”2-methylheptane”##, ##”octane”##.

The longer, and straighter the chain (i.e. the less unbranched) the greater should be the interaction between chains, and thus the greater the boiling point.

Now of course I did not know these boiling points off the top of my head, but I can account for their order:

##”2,2,4-trimethylheptane,”## ##99## ##””^@C##

##”2-methylheptane,”## ##116## ##””^@C##

##”octane”, 125## ##””^@C##

Longer, less branched chains have greater opportunity for intermolecular dispersion forces, and this is certainly reflected in the boiling point. That the longest chain alkane, ##”octane”##, is the most involatile supports our analysis. And even though ##”2,2,4-trimethylheptane”## is the most massive molecule, branching prevents as effective intermolecular interaction as exists in the other pair.

The boiling point of ##n-“heptane”## is ##98.5## ##””^@C## (this I did know off the top of my head, because I found it to be a highly useful laboratory solvent), which is comparable to the boiling point of
##”2,2,4-trimethylheptane”##. Once again, branching serves to decrease the boiling point.

Show more







Calculate Your Essay Price
(550 words)

Approximate price: $22

Calculate the price of your order

550 words
We'll send you the first draft for approval by September 11, 2018 at 10:52 AM
Total price:
$26
The price is based on these factors:
Academic level
Number of pages
Urgency
Basic features
  • Free title page and bibliography
  • Unlimited revisions
  • Plagiarism-free guarantee
  • Money-back guarantee
  • 24/7 support
On-demand options
  • Writer’s samples
  • Part-by-part delivery
  • Overnight delivery
  • Copies of used sources
  • Expert Proofreading
Paper format
  • 275 words per page
  • 12 pt Arial/Times New Roman
  • Double line spacing
  • Any citation style (APA, MLA, Chicago/Turabian, Harvard)

Our guarantees

Delivering a high-quality product at a reasonable price is not enough anymore.
That’s why we have developed 5 beneficial guarantees that will make your experience with our service enjoyable, easy, and safe.

Money-back guarantee

You have to be 100% sure of the quality of your product to give a money-back guarantee. This describes us perfectly. Make sure that this guarantee is totally transparent.

Read more

Zero-plagiarism guarantee

Each paper is composed from scratch, according to your instructions. It is then checked by our plagiarism-detection software. There is no gap where plagiarism could squeeze in.

Read more

Free-revision policy

Thanks to our free revisions, there is no way for you to be unsatisfied. We will work on your paper until you are completely happy with the result.

Read more

Privacy policy

Your email is safe, as we store it according to international data protection rules. Your bank details are secure, as we use only reliable payment systems.

Read more

Fair-cooperation guarantee

By sending us your money, you buy the service we provide. Check out our terms and conditions if you prefer business talks to be laid out in official language.

Read more

Order your essay today and save 10% with the coupon code: best10