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How does ionization energy change on the periodic table?

Chemistry Homework Help D

Ionization energy increases across a period and decreases down a group.

First: what is ionization energy ? It’s the minimum amount of energy required to remove an electron (to infinity) from the atom or molecule in the gaseous state

These are the factors that affect ionization energy:

  1. Atomic radius
  2. Nuclear charge
  3. Orbital penetration
  4. Electron pairing within a sub-shell
  5. Shielding or screening effect of the inner orbitals

Atomic radius:

  • When an atomic radius decreases, ionization energy increases.
  • Across a period, atomic radius decreases. Down a group, atomic radius increases. Therefore, across a period ionization energy increases down a group it decreases.

Nuclear charge:

  • If a nucleus has a positive charge, there is a stronger attraction for the electrons. This results in a high amount of ionization energy.
  • Across a period, attraction of electrons from the nucleus increases, while down a group it decreases. Therefore, across a period ionization energy increases down a group it decreases.

Orbital penetration:

  • Since the s orbitals penetrate towards the nucleus more closely than the p orbitals, it’s easier to remove electrons from p orbitals than from s orbitals.
  • Therefore, across a period ionization energy increases down a group it decreases.

Electron pairing within a sub-shell:

  • Since repulsion between electrons in the same orbital is higher than repulsion between electrons in different orbitals, within a sub-shell, paired electrons are easier to remove than unpaired ones.
  • Across a period ionization energy increases, down a group it decreases.

Shielding or screening effect of the inner orbitals:

  • Electrons in the outermost orbitals feel lesser attraction from the nucleus than expected, due to presence of electrons in inner orbitals.
  • Therefore, across a period ionization energy increases, down a group it decreases.

Overall: across a period ionization energy increases and down a group ionization energy decreases.

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