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I am not sure what you are asking, but D-glucose and D-fructose are constitutional isomers.
The structures of D-fructose and D-glucose are
They each have the same molecular formula, ##”C”_6″H”_12″O”_6##.
But D-fructose has a primary alcohol at ##”C-1″## and a ketone at ##”C-2″##.
And D-glucose has an aldehyde at ##”C-1″## and a secondary alcohol at ##”C-2″##.
This makes them constitutional isomers, because they have the same formula but a different order of bonding.
Beyond this, we can say that they are both hexoses, but one is a ketohexose and the other is an aldohexose.
Also, D-fructose is levorotatory, but D-glucose is dextrorotatory.
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