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Dibenzalacetone does not undergo the aldol condensation.
However, dibenzalacetone is formed by a crossed aldol condensation between benzaldehyde and acetone.
Some of the side products expected in this reaction could be:
From incomplete condensation of the benzaldehyde.
2. Diacetone alcohol (4-hydroxy-4-methylpentan-2-one) and mesityl oxide (4-methylpent-3-en-2-one)
From the aldol condensation of acetone with itself, followed by dehydration of the β-hydroxyketone.
##2″CH”_3″COCH”_3 → underbrace((“CH”_3)_2″C(OH)CH”_2″COCH”_3)_color(red)(“diacetone alcohol”) → underbrace((“CH”_3)_2″C=CHCOCH”_3)_color(red)(“mesityl oxide”) ##
3. Benzyl alcohol and benzoic acid from the Cannizzaro reaction of benzaldehyde.
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