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Ionization is a special case of dissociation.
Dissociation is a process in which separate or split into smaller particles.
We might write the general equation as
##”A-B” → “A + B”##
##”NaCl(s)” → “Na”^+”(aq)” + “Cl”^”-“”(aq)”##
In this case, the solid ##”NaCl”## consists of ##”Na”^+## and ##”Cl”^”-“## ions.
All they are doing when ##”NaCl”## dissolves is separating from each other.
When the substance already contains ions, the process is often called dissociation.
Many also dissociate in water to form ions.
##”HF(aq)” ⇌ “H”^+”(aq)” + “F”^”-“”(aq)”##
When covalent compounds dissolve in water to produce ions, the dissociation process is often called ionization.
Here’s a great video on ionization and dissociation.
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